Litcius/Paper detail

Study into influence of different types of igniters on the explosion parameters of dispersed nitrocellulose powder

Richard Kuracina, Zuzana Szabová, László Kosár, Martin Sahul

2023Journal of Loss Prevention in the Process Industries15 citationsDOIOpen Access PDF

Abstract

Nitrocellulose is a flammable compound produced by cellulose nitration. The nitrocellulose production and handling are associated with a risk of fire and explosion. Nitrocellulose is used as either collodion cotton (<12.5% N) or as an explosive (>12.5% N). Nitrocellulose is a fibrous or powdered substance and may detonate or burn upon certain conditions. The article compares the combustion parameters of dry nitrocellulose in the KV-150M2-UIBE explosion chamber at the concentrations of 250, 500 and 750 g m−3. To ignite a nitrocellulose sample, six different types of igniters were used. A commercially available 5 kJ pyrotechnic igniter was used as the standard. Also used were a nitrocellulose igniter, a pyrotechnic igniter with magnesium powder and KNO3/KClO3, and an exploding wire (Kanthal and tungsten wire). The examined igniters were found to affect the explosion parameters of dispersed nitrocellulose. The deviation of the explosion constant Kst reached 50% of the standard value. The highest pressure of 12.73 bar g was reached at a concentration of 750 g m−3 and an igniter exploding wire with Kanthal wire. The highest Kst value of 287.9 bar.m.s−1 was achieved at a concentration of 750 g m−3, when using the pyrotechnic igniter with KClO3 and magnesium powder.

Topics & Concepts

NitrocelluloseMaterials scienceSteam explosionExplosive materialFlammable liquidCombustionNitromethaneComposite materialMagnesiumChemistryMetallurgyPulp and paper industryBiochemistryMembraneEngineeringOrganic chemistryCombustion and Detonation ProcessesEnergetic Materials and CombustionEngineering and Material Science Research
Study into influence of different types of igniters on the explosion parameters of dispersed nitrocellulose powder | Litcius