Exploration of Alkyl Group Effects on the Molecular Packing of 5,15-Disubstituted Tetrabenzoporphyrins toward Efficient Charge-Carrier Transport
Eunjeong Jeong, Tatsuya Itô, Kohtaro Takahashi, Tomoyuki Koganezawa, Hironobu Hayashi, Naoki Aratani, Mitsuharu Suzuki, Hiroko Yamada
Abstract
even after heating at 160 °C in air, reflecting the tight packing of large BP units. These findings will serve as a good basis for extracting the full potential of 2D extended π-frameworks and thus for increasing the structural or functional diversities of high-performance organic semiconductors.
Topics & Concepts
StackingMaterials scienceOrganic semiconductorAlkylSemiconductorElectron mobilityField-effect transistorOptoelectronicsChemical physicsNanotechnologyTransistorOrganic chemistryChemistryPhysicsQuantum mechanicsVoltageOrganic Electronics and PhotovoltaicsConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry