Recent progress and perspectives in photo-induced organic reactions of acylsilanes
Wan Pyo Hong, Y. H. Shin, Inji Shin
Abstract
This review provides recent advances and insights into photoirradiation reactions of acylsilanes, notably via key nucleophilic siloxycarbene intermediates. Nucleophilic addition, insertion reaction, and cyclization are discussed in terms of reaction mechanism and scope.
Topics & Concepts
ChemistryNucleophileScope (computer science)Nucleophilic additionMechanism (biology)Combinatorial chemistryPhotochemistryOrganic chemistryCatalysisComputer scienceProgramming languagePhilosophyEpistemologyN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions