Exploring the Influence of ZnF<sub>2</sub> on Zinc-Tellurite Glass: Unveiling Changes in OH Content, Structure, and Optical Properties
Renato Grigolon Capelo, Ricardo Santos Baltieri, Marcos de Oliveira, Danilo Manzani
Abstract
High Resolution Image Download MS PowerPoint Slide Tellurite glasses have garnered considerable interest as optical host materials due to their advantageous properties, including low processing temperature, high resistance to corrosion and crystallization, and excellent solubility for rare earth ions. However, their applicability in the infrared (IR) region is limited by the absorption of species with distinct vibrations. The incorporation of fluorides has emerged as a promising approach to reduce hydroxyl (OH) absorption during the precursor melting process. In this study, we investigated the influence of ZnF 2 on a glass matrix composed of TeO 2 -ZnO-Na 2 O, resulting in notable changes in the glass structure and optical properties, with Eu 3+ serving as an environmental optical probe. The samples underwent comprehensive structural, thermal, and optical characterization. Structural analyses encompassed 19 F and 125 Te nuclear magnetic resonance (NMR), with the latter being complemented by mathematical simulations, and these findings were consistent with observations from Raman scattering. The main findings indicate an enhancement in thermal stability, modifications in the Te–O connectivity, and a reduction in emission intensity attributed to the effects of ligand polarizability and symmetry changes around Eu 3+ . Additionally, the fluorotellurite matrices exhibited a shift in the absorption edge toward higher energies, accompanied by a decrease in mid-IR absorptions, thereby expanding the transparency window. As a result, these glass matrices hold substantial potential for applications across various regions of the electromagnetic spectrum, including optical fiber drawing and the development of solid-state emitting materials.