Reduction of nitrite to nitric oxide and generation of reactive chalcogen species by mononuclear Fe(<scp>ii</scp>) and Zn(<scp>ii</scp>) complexes of thiolate and selenolate
Sayan Atta, Amit Kumar Mandal, Rahul Saha, Amit Majumdar
Abstract
A comparative study of isostructural Zn( ii ) and Fe( ii ) compounds for their reactivity with nitrite, transfer of the coordinated thiolate/selenolate and generation and transfer of reactive sulfur/selenium species is presented.
Topics & Concepts
ChalcogenNitriteSeleniumChemistryReactivity (psychology)Nitric oxideSulfurYield (engineering)Medicinal chemistryInorganic chemistryNuclear chemistryCrystallographyOrganic chemistryMaterials scienceMetallurgyMedicineNitrateAlternative medicinePathologyNitric Oxide and Endothelin EffectsVanadium and Halogenation ChemistryOrganoselenium and organotellurium chemistry