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Selectivity in the Elaboration of Bicyclic Borazarenes

Ayan Bhattacharjee, Geraint H. M. Davies, Borna Saeednia, Steven R. Wisniewski, Gary A. Molander

2020Advanced Synthesis & Catalysis41 citationsDOIOpen Access PDF

Abstract

Among aromatic compounds, borazarenes represent a significant class of isosteres in which carbon-carbon bonds have been replaced by B-N bonds. Described herein is a summary of the selective reactions that have been developed for known systems, as well as a summary of computationally-based predictions of selectivities that might be anticipated in reactions of yet unrealized substructures.

Topics & Concepts

ChemistryBicyclic moleculeElaborationSelectivityCarbon fibersCombinatorial chemistryOrganic chemistryStereochemistryCatalysisComposite numberHumanitiesPhilosophyComposite materialMaterials scienceOrganoboron and organosilicon chemistrySynthesis and Properties of Aromatic CompoundsOrganometallic Complex Synthesis and Catalysis