Microscopic Dynamics and Viscoelasticity of Vitrimers
Alessandro Perego, Daria Lazarenko, Michel Cloître, Fardin Khabaz
Abstract
We implement a hybrid molecular dynamics/Monte Carlo simulation to study the microscopic dynamics and the macroscopic rheology of vitrimers with a fast bond exchange rate. We show that the linear viscoelastic properties and mean squared displacement of the vitrimers collapse onto master curves by applying the same shift factors that follow the Williams–Landel–Ferry equation at low temperatures and Arrhenius-like behavior at high temperatures. The linkage between the microscopic dynamics and the linear rheology of vitrimers is established using the generalized Stokes–Einstein relationship, which efficiently extends the timescale of simulations and predicts the viscoelasticity. The values of the shift factors are related to the characteristic decay time of the intermediate scattering function, which is accessible in scattering experiments. The same results hold in the case of an all-atom model of an ionic liquid. Our methodology provides a microscopic basis for the time-superposition principle and predicts the macroscopic rheology of thermo-rheologically simple vitrimers.