Experimental and Computational Studies on Cp*<sup>Cy</sup>Rh(III)/KOPiv-Catalyzed Intramolecular Dehydrogenative Cross-Couplings for Building Eight-Membered Sultam/Lactam Frameworks
Liping Li, Hui Gao, Ming Sun, Zhi Zhou, Wei Yi
Abstract
Rh(III) catalysis with redox-neutral and highly atom-economical features.
Topics & Concepts
Intramolecular forceChemistryCatalysisLactamBeta-lactamStereochemistryMedicinal chemistryCombinatorial chemistryOrganic chemistryBiochemistryAntibioticsCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsSulfur-Based Synthesis Techniques