Solubilized LiNO<sub>3</sub>by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte
Jing Zhao, Zhengwei Wan, Xiaomin Zeng, Miaomiao Tian, Kun Wang, Xinyu Chen, Min Ling, Wenbin Ni, Chengdu Liang
Abstract
CsF solubilized LiNO 3 to optimize solvated shell of Li + in carbonate electrolyte. LiF-rich SEI was generated to prevent severe side reactions of Li metal. Cs + can inhibit lithium dendrite formation by self-healing electrostatic shield mechanism.
Topics & Concepts
ElectrolyteDendrite (mathematics)Lithium (medication)Cationic polymerizationLithium metalLithium carbonateInorganic chemistryMetalChemistryAnodeSolubilizationChemical engineeringMaterials scienceIonPolymer chemistryOrganic chemistryPhysical chemistryIonic bondingElectrodeEngineeringGeometryMathematicsEndocrinologyMedicineBiochemistryAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research