Simple magnetization of Fe<sub>3</sub>O<sub>4</sub>/MIL‐53(Al)‐NH<sub>2</sub> for a rapid vortex‐assisted dispersive magnetic solid‐phase extraction of phenol residues in water samples
Tittaya Boontongto, Rodjana Burakham
Abstract
Abstract The present work describes a simple route to magnetize MIL‐53(Al)‐NH 2 sorbent for rapid extraction of phenol residues from environmental samples. To extend the applications and performances of the metal‐organic frameworks in the field of adsorption materials, we combined the properties of metal‐organic frameworks and magnetite to decrease the extraction time and simplify the extraction process as well. In this study, a simple and quick vortex‐assisted dispersive magnetic solid phase extraction method for the extraction of ten United States Environmental Protection Agency's priority phenols from water samples prior to analysis by high‐performance liquid chromatography with photodiode array detection was proposed. The developed method exhibits a rapid enrichment of the target analytes within 10 s for extraction and 10 s for desorption. Low detection limits of 1.8‐41.7 µg/L and quantitation limits of 6.0‐139.0 µg/L with the relative standard deviations for intra‐ and interday analyses less than 12% were achieved. Satisfactory recoveries in the range of 80‐111% with the relative standard deviations less than 11% demonstrated that Fe 3 O 4 /MIL‐53(Al)‐NH 2 is promising sorbent in the field of magnetic solid‐phase extraction for environmental samples.