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Metal-free visible-light-induced aerobic oxidation of α-diazoesters leading to α-ketoesters in air

Ruisheng Liu, Qishun Liu, Haoran Meng, Hongyu Ding, Jindong Hao, Zhongyin Ji, Huilan Yue, Wei Wei

2021Organic Chemistry Frontiers39 citationsDOI

Abstract

A metal-free and visible-light-induced strategy has been established for the construction of α-ketoesters <italic>via</italic> aerobic oxidation of α-diazoesters with dioxygen in air at room temperature.

Topics & Concepts

ChemistryPhotochemistryMetalVisible spectrumMolecular oxygenBare metalOxygenOrganic chemistryOptoelectronicsStentSurgeryMedicineRestenosisPhysicsCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsRadical Photochemical Reactions
Metal-free visible-light-induced aerobic oxidation of α-diazoesters leading to α-ketoesters in air | Litcius