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Photoinduced C–H monofluoroalkenylation with <i>gem</i>-difluoroalkenes through hydrogen atom transfer under batch and flow conditions

Chenlin Cao, Guangxu Zhang, Fei Xue, Hong‐Ping Deng

2021Organic Chemistry Frontiers36 citationsDOI

Abstract

A mild and effective protocol for the monofluoroalkenylation of C–H bonds with gem -difluoroalkenes through the synergetic merger of photoredox and bromine-based hydrogen atom transfer catalysis under batch and flow conditions is reported.

Topics & Concepts

ChemistryHydrogen atomCatalysisPhotoredox catalysisPhotochemistryBromineCombinatorial chemistryOrganic chemistryAlkylPhotocatalysisFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods
Photoinduced C–H monofluoroalkenylation with <i>gem</i>-difluoroalkenes through hydrogen atom transfer under batch and flow conditions | Litcius