Litcius/Paper detail

Microstructure and mechanical properties of spark plasma‐sintered La <sub>2</sub> O <sub>3</sub> dispersion‐strengthened W–Ni–Fe alloy

Muthuchamy AyyappaRaj, Digvijay Yadav, Dinesh Agrawal, Raja Annamalai Arunjunai Rajan

2020Rare Metals20 citationsDOI

Abstract

Abstract An investigation of lanthanum oxide (La 2 O 3 ) addition to tungsten heavy alloy (WHA) with a ternary composition of W–7Ni–3Fe was reported in this study. The mixed powders were sintered using spark plasma sintering (SPS) technique. La 2 O 3 was added in increments of 0.25 wt%, 0.50 wt%, 0.75 wt% and 1.00 wt% to WHA, respectively. The sintered samples were characterized for microstructural evolution and mechanical properties. The influences of La 2 O 3 addition on density, grain size, hardness, ultimate tensile strength (UTS) and ductility on W–7Ni–3Fe system were discussed in this study. The highest relative sintered density of 87.95% was obtained for 0.25 wt% La 2 O 3 addition to W–7Ni–3Fe. The lowest grain size of 7.89 μm was observed for 1.00 wt% La 2 O 3 addition. Similarly, the highest hardness and UTS of HV 533 and 1110 MPa, respectively, were also obtained for the same composition. Scanning electron microscopy (SEM) and energy‐dispersive spectroscopy (EDS) of the samples revealed homogenous distribution of La 2 O 3 in the alloy matrix. Fractography of the sintered alloy samples revealed W–W intergranular fracture.

Topics & Concepts

Materials scienceSpark plasma sinteringMicrostructureIntergranular fractureScanning electron microscopeAlloyUltimate tensile strengthLanthanum oxideFractographySinteringMetallurgyGrain sizeDuctility (Earth science)Relative densityEnergy-dispersive X-ray spectroscopyComposite materialGrain boundaryOxideCreepAdvanced materials and compositesMetal and Thin Film MechanicsFusion materials and technologies