Fates of Organic Hydroperoxides in Atmospheric Condensed Phases
Shinichi Enami
Abstract
is a key process for the decomposition of ROOHs that bypasses radical formation. In this perspective, we discuss our current understanding of the aqueous-phase decomposition of atmospherically relevant ROOHs, including ROOHs derived from reaction between Criegee intermediates and alcohols or carboxylic acids, and of highly oxygenated molecules (HOMs). Implications and future challenges are also discussed.
Topics & Concepts
ChemistryDecompositionChlorideAqueous solutionAdductOrganic chemistryRadicalPhotochemistryComputational chemistryAtmospheric chemistry and aerosolsAir Quality and Health ImpactsAtmospheric Ozone and Climate