Palladium-Nanoparticles Biohybrids in Applied Chemistry
Marco Filice, Noelia Losada‐Garcia, Carlos Perez-Rizquez, Marzia Marciello, M. P. Morales, José M. Palomo
Abstract
Applied nanotechnology has experienced tremendous advance over the last decade. In this study, the efficient synthesis of highly stable palladium-nanoparticles (PdNPs) biohybrids based on the application of an enzyme, which induces in situ the generation of spherical nanoparticles on the protein network, has been described. A heterogeneous material was synthesized formed with PdNPs with average sizes between 1.5 to 5 nm. These Pd nanocatalysts were successfully applied in different chemical processes: C-C bonding reactions (Suzuki and Heck reactions) and cascade processes combining enzymatic and metallic activities (hydrolysis-reduction, esterification-racemization).