Regulating electron transfer and orbital interaction within metalloporphyrin-MOFs for highly sensitive NO<sub>2</sub> sensing
Er‐Xia Chen, Liang He, Mei Qiu, Yongfan Zhang, Yayong Sun, Wenhua Li, Jian‐Ze Xiao, Jie Chen, Gang Xu, Qipu Lin
Abstract
The electron transfer pathways and orbital interactions between analytes and adsorption sites in gas-sensing were evaluated using isoreticular catechol–metalloporphyrin scaffolds.
Topics & Concepts
CatecholElectron transferAdsorptionChemistryElectronPhotochemistryChemical physicsNanotechnologyMaterials scienceOrganic chemistryPhysicsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsMolecular Sensors and Ion Detection