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Orthogonally aligned cyclic BODIPY arrays with long-lived triplet excited states as efficient heavy-atom-free photosensitizers

Zhaoyang Zhu, Xue Zhang, Xing Guo, Qinghua Wu, Zhongxin Li, Changjiang Yu, Erhong Hao, Lijuan Jiao, Jianzhang Zhao

2021Chemical Science47 citationsDOIOpen Access PDF

Abstract

Cyclic BODIPY trimers showed strong exciton coupling in singlet excited states and long-lived triplet excited states, and generated both singlet oxygen and superoxide radicals under light irradiation, giving good reactive oxygen quantum yields and promising PDT results in vitro .

Topics & Concepts

Excited statePhotochemistryBODIPYSinglet oxygenChemistryRadicalAtom (system on chip)Singlet stateSinglet fissionExcitonCoupling (piping)OxygenAtomic physicsMaterials scienceFluorescencePhysicsOrganic chemistryEmbedded systemComputer scienceQuantum mechanicsMetallurgyLuminescence and Fluorescent MaterialsNanoplatforms for cancer theranosticsPerovskite Materials and Applications
Orthogonally aligned cyclic BODIPY arrays with long-lived triplet excited states as efficient heavy-atom-free photosensitizers | Litcius