Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene
Taito Hashimoto, Ryusei Oketani, Asato Inoue, Kohei Okubo, Kouki Oka, Norimitsu Tohnai, Kazuhide Kamiya, Shuji Nakanishi, Ichiro Hisaki
Abstract
Aperture shape and size of flexible hydrogen-bonded organic frameworks (HOF) were statically modulated using various aromatic solvents, and dynamically changed by desorption and adsorption of the solvent molecules.
Topics & Concepts
PyreneHydrogenChemistryCombinatorial chemistryPolymer chemistryComputer scienceMaterials sciencePhotochemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsLuminescence and Fluorescent Materials