Rational direct synthesis of [Fe(Htrz)<sub>2</sub>(trz)](BF<sub>4</sub>) polymorphs: temperature and concentration effects
Marlène Palluel, Liza El Khoury, Nathalie Daro, Sonia Buffière, Michaël Josse, Mathieu Marchivie, Guillaume Chastanet
Abstract
Rational design of [Fe(Htrz)<sub>2</sub>trz](BF<sub>4</sub>) spin crossover (SCO) polymorphs through the study of the phase diagram and structure refinement.
Topics & Concepts
Spin crossoverPhase diagramChemistryCrystal structurePolymorphism (computer science)CrystallographyPhase (matter)Materials scienceOrganic chemistryGeneBiochemistryGenotypeMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal complexes synthesis and properties