Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes <i>via</i> intermolecular bimetallic cooperation
Ekaterina S. Gulyaeva, Elena S. Osipova, Sergey A. Kovalenko, Oleg A. Filippov, Natalia V. Belkova, Laure Vendier, Yves Canac, Elena S. Shubina, Dmitry A. Valyaev
Abstract
(TON up to 18 200) that is largely superior to all known 3d-, s-, p-, f-block metal derivatives and frustrated Lewis pairs (FLPs). These results represent a step forward towards more extensive use of intermolecular bimetallic cooperation concepts in modern homogeneous catalysis.
Topics & Concepts
Bimetallic stripDehydrogenationCatalysisBoranesHalideAmine gas treatingChemistryMetalIntermolecular forceOrganic chemistryCombinatorial chemistryMoleculeBoronHydrogen Storage and MaterialsCarbon dioxide utilization in catalysisAmmonia Synthesis and Nitrogen Reduction