A biphosphine copolymer encapsulated single-site Rh catalyst for heterogeneous regioselective hydroaminomethylation of alkenes
Kang Zhao, Hongli Wang, Xinzhi Wang, Xinjiang Cui, Feng Shi
Abstract
) was developed and employed in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity by a one-pot method. The combined actions of hierarchical pore confinement and the biphosphine ligand derived from the POP catalyst contributed to the improved regioselectivity.
Topics & Concepts
RegioselectivityCatalysisChemistryCopolymerLigand (biochemistry)PorosityHeterogeneous catalysisRhodiumPolymer chemistryPolymerOrganic chemistryCombinatorial chemistryBiochemistryReceptorAsymmetric Hydrogenation and CatalysisCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis