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Compositional phase stability in medium-entropy and high-entropy Cantor-Wu alloys from an <i>ab initio</i> all-electron Landau-type theory and atomistic modeling

Christopher D. Woodgate, J. B. Staunton

2022Physical review. B./Physical review. B25 citationsDOIOpen Access PDF

Abstract

Short-range order in high-entropy alloys (HEA) prompts exciting physical questions: What are the implications for material properties, and what underlying mechanisms are drivers? In this theoretical work the authors describe a rigorous, first-principles approach combined with atomistic modeling to assess the nature of compositional order in the prototypical HEA, NiCoFeMnCr, and its derivatives. In particular, this work shows that finding the range of interactions, and representing the resulting behavior in reciprocal space, is important for understanding the stability of these materials.

Topics & Concepts

Statistical physicsReciprocalHigh entropy alloysEntropy (arrow of time)Reciprocal latticeStability (learning theory)Materials scienceThermodynamicsPhysicsComputer sciencePhase (matter)Machine learningQuantum mechanicsPhilosophyDiffractionLinguisticsHigh Entropy Alloys StudiesHigh-Temperature Coating BehaviorsAdvanced materials and composites
Compositional phase stability in medium-entropy and high-entropy Cantor-Wu alloys from an <i>ab initio</i> all-electron Landau-type theory and atomistic modeling | Litcius