Radical Hydroalkylation and Hydroacylation of Alkenes by the Use of Benzothiazoline under Thermal Conditions
Tatsuhiro Uchikura, Mitsuhiro Toda, Toshiki Mouri, Tatsuya Fujii, Kaworuko Moriyama, Ignacio Ibáñez, Takahiko Akiyama
Abstract
The hydroalkylation and hydroacylation of electron-deficient alkenes proceeded smoothly by using benzothiazoline derivatives as radical-transfer reagents under thermal conditions without light irradiation or any additive. Both benzyl and benzoyl moieties were transferred efficiently.
Topics & Concepts
HydroacylationChemistryReagentOrganic chemistryCombinatorial chemistryCatalysisRhodiumRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOxidative Organic Chemistry Reactions