Photoinduced triiodide-mediated [3 + 2] cycloaddition of <i>N</i>-tosyl aziridines and alkenes
Yuanbo Li, Fan Chen, Shengqing Zhu, Lingling Chu
Abstract
A photoinduced triiodide-mediated [3 + 2] cycloaddition of <italic>N</italic>-Ts aziridines and alkenes is described herein. This operationally simple protocol enables regioselective access to a wide range of substituted pyrrolidines under mild-free conditions.
Topics & Concepts
ChemistryTriiodideTosylCycloadditionRegioselectivityMedicinal chemistryCombinatorial chemistryPhotochemistryOrganic chemistryCatalysisElectrolyteDye-sensitized solar cellPhysical chemistryElectrodeSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsFluorine in Organic Chemistry