Microgel organocatalysts: modulation of reaction rates at liquid–liquid interfaces
Denise Kleinschmidt, Katja Nothdurft, Mikhail V. Anakhov, Anna A. Meyer, Matthias Mork, Rustam A. Gumerov, Igor I. Potemkin, Walter Richtering, Andrij Pich
Abstract
Responsive colloidal microgel-catalysts were applied to an aldol reaction to study how temperature and the effect of cononsolvency can be used as triggers to modulate reaction rates in homogenous phase and on liquid–liquid interfaces.
Topics & Concepts
Liquid liquidCatalysisColloidLiquid phaseAldol reactionReaction rateChemical engineeringMaterials scienceChemistryOrganic chemistryChromatographyThermodynamicsPhysicsEngineeringSurfactants and Colloidal SystemsPickering emulsions and particle stabilizationPolymer Surface Interaction Studies