Proton controlled synthesis of two dicopper(<scp>ii</scp>) complexes and their magnetic and biomimetic catalytic studies together with probing the binding mode of the substrate to the metal center
Narayan Ch. Jana, Pravat Ghorai, Paula Brandão, Zvonko Jagličić, Anangamohan Panja
Abstract
Synthesis of two closely related yet distinct doubly bridged dicopper(II) complexes, and their magnetic properties and bio-related catalytic activities together with probing the binding mode of the substrate to the metal center are reported.
Topics & Concepts
ChemistryBimetallic stripCatalysisLigand (biochemistry)ProtonationDenticitySchiff baseSubstrate (aquarium)StereochemistryAmine gas treatingMetalTertiary amineReactivity (psychology)CrystallographyCrystal structurePolymer chemistryOrganic chemistryReceptorPathologyGeologyIonOceanographyBiochemistryMedicineAlternative medicineMetal complexes synthesis and propertiesMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexes