Conformationally adaptable macrocyclic receptors for ditopic anions: analysis of chelate cooperativity in aqueous containing media
Stuart N. Berry, Lei Qin, William Lewis, Katrina A. Jolliffe
Abstract
H NMR and crystallographic studies confirmed the macrocycle hosts are adaptable, changing conformation to match their pore size to a selected guest.
Topics & Concepts
CooperativityChemistryChelationAqueous mediumReceptorAqueous solutionCombinatorial chemistryCooperative bindingStereochemistryOrganic chemistryBiochemistryBinding siteMolecular Sensors and Ion DetectionAnalytical Chemistry and ChromatographySupramolecular Chemistry and Complexes