ESIPT-PET based triphenylamine-anthraquinone probe for the detection of phosgene: DFT studies, real-time application in soil samples and test strips
Ramakrishnan AbhijnaKrishna, Sivan Velmathi
Abstract
H NMR spectroscopy, the mechanism for sensing was verified. The ESIPT and PET mechanism of the probe was confirmed through DFT and TDDFT studies. In addition, we could detect phosgene in soil samples with detection limits of 0.1583 ppm, 0.233 ppm and 1.047 ppm for field soil, clay soil and sandy soil, respectively, and created a fluorescent test strip to identify phosgene. The fluorescent test strip's colour change from light reddish to yellow is visible to the unaided eye under 365 nm UV light.
Topics & Concepts
PhosgeneTriphenylaminePhotochemistryChemistryDetection limitFluorescenceChromatographyOrganic chemistryQuantum mechanicsPhysicsMolecular Sensors and Ion DetectionElectrochemical Analysis and ApplicationsElectrochemical sensors and biosensors