Litcius/Paper detail

Biobased Epoxies Derived from Myrcene and Plant Oil: Design and Properties of Their Cured Products

Xuejuan Yang, Ming Guo, Xing Wang, Weiwei Huan, Minghui Li

2020ACS Omega13 citationsDOIOpen Access PDF

Abstract

) of cured samples increases from 17 to 71 °C with the increasing content of myrcene-based epoxy. Morphology of fracture surface indicates that the cured sample containing plant oil-based epoxy resin shows obvious plastic deformation. The curing kinetics of the two epoxies resin is studied by differential scanning calorimetry. Also, the calculated activation energy is 70.49 kJ/mol for myrcene-based epoxy and 64.02 kJ/mol for poly-fatty acid-derived epoxy resin. The thermogravimetric analysis indicates that the main degradation temperature of all cured samples is above 300 °C. The sustainable biobased epoxy has some potential in preparing flexible epoxy materials and can be used to toughen conventional petroleum-based epoxy.

Topics & Concepts

EpoxyMaterials scienceGlass transitionUltimate tensile strengthDifferential scanning calorimetryComposite materialThermogravimetric analysisCuring (chemistry)MyrcenePolymerChemistryOrganic chemistryLimonenePhysicsThermodynamicsEssential oilChromatographyPolymer composites and self-healingEpoxy Resin Curing ProcessesLignin and Wood Chemistry