Non-innocent P-centers in nonbenzenoid polycyclic aromatic molecules with tunable structures and properties
Can Li, Wei Zhou, Zhaoxin Liu, Rong Gao, Qixi Mi, Zhijun Ning, Yi Ren
Abstract
the P-centers. In particular, the PC derivative with a P(iii)-center showed unexpected room-temperature phosphorescence in solution, which was attributed to the excited-state aromaticity induced structure change at the P-center. Decoration with various aryl groups further modified the photophysical and redox properties in another dimension. Furthermore, bis(triarylamine)-functionalized P-PAMs formed stable radical cations in which the P-environments strongly influenced the mixed-valence state and open-shell characters. As a proof of concept, bis(triarylamine)-functionalized P-PAMs were explored as the hole-transporting layers in perovskite solar cells, and a power conversion efficiency of 14% was achieved. As a new example of nonbenzenoid PAMs with intriguing optoelectronic properties, our P-PAMs are promising building blocks for diverse optoelectronic applications in the future.