Regulation of <i>cis</i> and <i>trans</i> microstructures of isoprene units in alternating copolymers <i>via</i> “space-limited” living species in anionic polymerization
Qingchi Ma, Xuefei Leng, Li Han, Pibo Liu, Chao Li, Songbo Zhang, Lan Lei, Hongwei Ma, Yang Li
Abstract
Space-limited living species provide new insight into the regulation of the microstructure of isoprene units in alternating copolymers composed of isoprene and 1,1-bis(4-dimethylsilylphenyl)ethylene (DPE-2SiH).
Topics & Concepts
IsopreneCopolymerEthylenePolymerizationMicrostructurePolymer chemistryChemistrySpace (punctuation)Organic chemistryCatalysisCrystallographyPolymerComputer scienceOperating systemIonic liquids properties and applicationsAdvanced Polymer Synthesis and CharacterizationAnalytical Chemistry and Chromatography