Brønsted acid-catalyzed homogeneous O–H and S–H insertion reactions under metal- and ligand-free conditions
Zhipeng Zhang, Zhiqin He, Yuxing Xie, Tiantong He, Yaofeng Fu, Yang Yu, Fei Huang
Abstract
The economical and accessible CF<sub>3</sub>SO<sub>3</sub>H successfully catalyzed homogeneous O–H and S–H bond insertion reactions between hydroxyl compounds, thiols and diazo compounds under metal- and ligand-free conditions.
Topics & Concepts
ChemistryDiazoLigand (biochemistry)HomogeneousCatalysisMetalHomogeneous catalysisMedicinal chemistryPolymer chemistryOrganic chemistryReceptorPhysicsBiochemistryThermodynamicsCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions