Boridene: Two-dimensional Mo <sub>4/3</sub> B <sub>2-x</sub> with ordered metal vacancies obtained by chemical exfoliation
Jie Zhou, Justinas Pališaitis, Joseph Halim, Martin Dahlqvist, Quanzheng Tao, Ingemar Persson, Lars Hultman, Per O. Å. Persson, Johanna Rosén
Abstract
Boridene: a 2D boride A range of two-dimensional (2D) materials, including graphene and hexagonal boron nitride, have been synthesized and studied because of the unusual properties that occur when one dimension becomes very small. MXenes are a family of materials made of layers of inorganic transition metal carbides and nitrides that are a few atoms thick and are manufactured by selective etching. Attempts to make similar boridene materials have been challenging because of the reactive nature of boride phases and because the parent materials tend to dissolve rather than selectively etch. Zhou et al . synthesized boridene in the form of single-layer 2D molybdenum boride sheets by selective etching in aqueous hydrofluoric acid to produce sheets with ordered metal vacancies, opening up an additional family of materials for study. —MSL