Facile and practical hydrodehalogenations of organic halides enabled by calcium hydride and palladium chloride
Jingjing Gui, Xin Cai, Lingyun Chen, Yuxin Zhou, Wenjing Zhu, Yuanrui Jiang, Min Hu, Xiaobei Chen, Yanwei Hu, Shilei Zhang
Abstract
For the first time, calcium hydride and palladium chloride were used to reduce a wide range of organic halides including aromatic bromides, aromatic chlorides, aromatic triflates, aliphatic bromides, aliphatic chlorides and trihalomethyl compounds.
Topics & Concepts
ChemistryHalidePalladiumHydrideChlorideCalciumOrganic chemistryInorganic chemistryHydrogenCatalysisRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsEnvironmental remediation with nanomaterials