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Electromagnetic interference shielding properties of graphene <scp>quantum‐dots</scp> reinforced poly(vinyl alcohol)/polypyrrole blend nanocomposites

Priyanka Rani, M. Basheer Ahamed, Kalim Deshmukh

2020Journal of Applied Polymer Science58 citationsDOI

Abstract

Abstract Graphene quantum dots (GQDs) reinforced poly(vinyl alcohol) (PVA)/polypyrrole (WPPy) nanocomposite films with various GQDs loadings were synthesized using the versatile solvent casting method. The structural and morphological properties of PVA/WPPy/GQDs nanocomposite films were investigated by employing Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. The thermogravimetric analysis revealed enhanced thermal stability of synthesized nanocomposites while enhanced dielectric properties were also observed. The maximum dielectric constant value for PVA/WPPy/GQDs nanocomposite films was observed to be ε = 6,311.85 (50 Hz, 150°C). The electromagnetic interference (EMI) shielding effectiveness (SE) of nanocomposite films was determined in the X‐band (8–12 GHz) and Ku‐band (12–18 GHz) frequency region. The EMI SE was found to be increased from 0.8 dB for the pure PVA film to 9.8 dB for the PVA/WPPy/GQDs nanocomposite film containing 10 wt% GQDs loading. The enhanced EMI shielding efficiency of nanocomposite films has resulted from the homogenous dispersion of GQDs in PVA/WPPy blend nanocomposites. Thus, the prepared nanocomposites are envisioned to utilize as a lightweight, flexible, and low‐cost material for EMI shielding applications.

Topics & Concepts

NanocompositeMaterials scienceGrapheneVinyl alcoholThermogravimetric analysisPolypyrroleDielectricComposite materialFourier transform infrared spectroscopyThermal stabilityScanning electron microscopeNanoparticleChemical engineeringPolymerNanotechnologyPolymerizationOptoelectronicsEngineeringElectromagnetic wave absorption materialsDielectric materials and actuatorsAdvanced Antenna and Metasurface Technologies
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