Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates <i>via</i> energy transfer
Shuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan Li
Abstract
A transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.
Topics & Concepts
ChemistryAnnulationEnergy transferTransfer (computing)PhotochemistryOrganic chemistryComputer scienceParallel computingMolecular physicsCatalysisRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions