Chemically recycled commercial polyurethane (PUR) foam using 2-hydroxypropyl ricinoleate as a glycolysis reactant for flexibility-enhanced automotive applications
Vojtěch Jašek, Petr Montag, Přemysl Menčík, Radek Přikryl, Alena Kalendová, Silvestr Figalla
Abstract
H NMR cross-analysis. The laboratory experiments (565 mL) included rheological, structural, and reactivity investigations. Added 30% REC content decreased the apparent viscosity to 109 mPa s from standard 274 mPa s. The reactivity of the 30% REC system increased by 51.2% based on the cream time due to the high REC amine value. The block foam density of systems with 15% REC and above decreased by 14.8%. A system with 20% REC content was the most prospective for up-scale. The industrially significant up-scale (125 L) was performed successfully, and the tensile and flexural test specimens were sampled from the up-scaled foam. The tensile characteristic (tensile strength 107 ± 8 kPa and elongation 9.2 ± 0.7%) and flexural characteristic (flexural strength 156 ± 12 kPa and flexural strain at deformation limit 23.4 ± 0.6%) confirmed that the REC incorporation in the standard PUR foam improves the applicable significant mechanical properties and assures the manufacture improve.