Decomposition mechanism of α-alkoxyalkyl-hydroperoxides in the liquid phase: temperature dependent kinetics and theoretical calculations
Mingxi Hu, Kunpeng Chen, Junting Qiu, Ying‐Hsuan Lin, Kenichi Tonokura, Shinichi Enami
Abstract
The decomposition rates of organic hydroperoxides derived from ozonolysis of terpene-alcohol in the presence of short-chain alcohols in aqueous organic media is markedly increased as the temperature is increased.
Topics & Concepts
DecompositionKineticsLiquid phaseMechanism (biology)ThermodynamicsPhase (matter)ChemistryPhysical chemistryMaterials scienceComputational chemistryOrganic chemistryPhysicsClassical mechanicsQuantum mechanicsAtmospheric chemistry and aerosolsChemical Reactions and MechanismsCatalytic Processes in Materials Science