Configuration-controllable synthesis of <i>Z</i>/<i>E</i> isomers based on <i>o</i>-carborane-functionalized tetraphenylethene
Qin Zhou, Miao Zhu, Wei Chen, Na Qin, Yujie Liu, Weihua Zhang, Xiang Li, Ye Sha, Hong Yan
Abstract
Two <italic>Z</italic>/<italic>E</italic> isomers, namely, <bold>Z-TPE-2Car</bold> and <bold>E-TPE-2Car</bold>, with clear configuration were synthesized using an effective route and have high solid-state fluorescence quantum yields, reaching 99% and 90%, respectively.
Topics & Concepts
ChemistryCarboraneStereochemistryLuminescence and Fluorescent MaterialsBoron Compounds in ChemistryPorphyrin and Phthalocyanine Chemistry