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Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

Megan Keener, Maxwell Mattejat, Shao‐Liang Zheng, Guang Wu, Trevor W. Hayton, Gabriel Ménard

2022Chemical Science19 citationsDOIOpen Access PDF

Abstract

Redox-switchable carboranes electrochemically capture and release UO 2 2+ selectively from mixed metal aqueous solutions, mimicking in part spent nuclear fuel.

Topics & Concepts

ActinideUranylLanthanideAlkali metalElectrochemistryAqueous solutionChemistryInorganic chemistryRedoxPhysical chemistryOrganic chemistryElectrodeIonRadioactive element chemistry and processingChemical Synthesis and CharacterizationRadiopharmaceutical Chemistry and Applications
Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes | Litcius