Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides
Kunlang Ji, Khalid N. Alharbi, Elena Solana‐Madruga, G.T. Moyo, C. Ritter, J. Paul Attfield
Abstract
Abstract Control of cation ordering in ABX 3 perovskites is important to structural, physical and chemical properties. Here we show that thermal transformations of AA′BB′O 6 double double perovskites, where both A and B sites have 1:1 cation order, to (A 0.5 A′ 0.5 ) 2 BB′O 6 double perovskites with fully disordered A/A′ cations can be achieved under pressure in CaMnMnWO 6 and SmMnMnTaO 6 , enabling both polymorphs of each material to be recovered. This leads to a dramatic switch of magnetic properties from ferrimagnetic order in double double perovskite CaMnMnWO 6 to spin glass behaviour in the highly frustrated double perovskite polymorph. Comparison of double double and double perovskite polymorphs of other materials will enable effects of cation order and disorder on other properties such as ferroelectricity and conductivity to be explored.