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Stereolithographic 3D printing of pure poly(ether–ester) networks from spirocyclic monomers <i>via</i> cationic ring-opening photopolymerization at high temperatures

Danijela Kojić, Katharina Ehrmann, Raffael Wolff, Yazgan Mete, Thomas Koch, Jürgen Stampfl, Stefan Baudis, Robert Liska

2023Polymer Chemistry13 citationsDOIOpen Access PDF

Abstract

We demonstrate stereolithographic 3D printing of pure aliphatic poly(ether esters) from spiro-orthoesters with near-net-zero shrinkage and significantly reduced shrinkage stress.

Topics & Concepts

PhotopolymerCationic polymerizationMonomerRing-opening polymerizationPolymer chemistryEtherRing (chemistry)Chemistry3D printingMaterials sciencePolymerOrganic chemistryComposite materialPhotopolymerization techniques and applicationsAdditive Manufacturing and 3D Printing TechnologiesAdvanced Polymer Synthesis and Characterization
Stereolithographic 3D printing of pure poly(ether–ester) networks from spirocyclic monomers <i>via</i> cationic ring-opening photopolymerization at high temperatures | Litcius