Unravelling kinetic and mass transport effects on two-electron storage in radical polymer batteries
Kai Zhang, Yuan Xie, Benjamin B. Noble, Michael J. Monteiro, Jodie L. Lutkenhaus, Kenichi Oyaizu, Zhongfan Jia
Abstract
Electron transfer and mass transport kinetics between two redox couples in nitroxide radical polymers was investigated. Such impact on two-electron storage in radical polymer batteries was exemplified by two macromolecular structures.
Topics & Concepts
PolymerKinetic energyElectron transferElectronMass transportKineticsElectron transport chainNitroxide mediated radical polymerizationMass transferRedoxChemistryRadical ionPhotochemistryChemical physicsPolymer chemistryMaterials scienceIonRadical polymerizationOrganic chemistryEngineering physicsCopolymerPhysicsChromatographyBiochemistryQuantum mechanicsConducting polymers and applicationsAdvanced battery technologies researchOrganic Electronics and Photovoltaics