The cooperative role of innocent ligand in <i>N</i>-heterocyclic carbene manganese catalyzed carbon dioxide hydrogenation
Yaru Jing, Jiahao Liu, Zongren Ye, Jiaqi Su, Yan Liu, Zhuofeng Ke
Abstract
The concept of Lewis acidic π* cooperation was proposed for innocent CO ligand in NHC–Mn catalyzed CO 2 hydrogenation by systematic DFT studies.
Topics & Concepts
CarbeneCatalysisManganeseLigand (biochemistry)ChemistryCarbon dioxideLewis acids and basesMedicinal chemistryCombinatorial chemistryOrganic chemistryReceptorBiochemistryCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisN-Heterocyclic Carbenes in Organic and Inorganic Chemistry