Liquid‐Like Phase of <i>N</i>,<i>N</i>‐Dimethylpyrrolidinium Iodide Impregnated into COFs Endows Fast Lithium Ion Conduction in the Solid State
Zhenhua Wu, Qinchao Xu, Juan Li, Xian‐Ming Zhang
Abstract
Abstract A novel kind of solid‐state lithium electrolyte was fabricated by impregnating organic ionic plastic crystals (OIPCs) into the pores of covalent organic frameworks (COFs). The liquid‐like phase of confined N , N ‐dimethylpyrrolidinium iodide (P 1,1 I) and the ordered nanochannels of COFs simultaneously stimulated the lithium ion conduction.
Topics & Concepts
Lithium (medication)IodideLithium iodideCovalent bondElectrolyteMaterials scienceIonPhase (matter)Solid-stateIonic liquidIonic conductivityChemical engineeringIonic bondingInorganic chemistryPolymer chemistryNanotechnologyChemistryPhysical chemistryOrganic chemistryElectrodeMedicineCatalysisEngineeringEndocrinologyCovalent Organic Framework ApplicationsAdvanced Battery Materials and TechnologiesMetal-Organic Frameworks: Synthesis and Applications