Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one
Yang Xu, Hongkai Wang, Zhuang Yang, Yuqiao Zhou, Yangbin Liu, Xiaoming Feng
Topics & Concepts
BenzofuranChemistryCombinatorial chemistryCatalysisTsuji–Trost reactionNatural productPhosphoramiditeTotal synthesisAlkylationStereochemistryStereoselectivityDesymmetrizationEnantioselective synthesisOrganic chemistryOligonucleotideBiochemistryDNAPhytochemical compounds biological activitiesTraditional and Medicinal Uses of AnnonaceaeMarine Sponges and Natural Products