Unraveling the Spatiotemporal Heterogeneity in the Oxidation Potential of Fine Particulate Matter in China
Yiheng Wang, Guochao Chen, Ting Liu, Peng Wang, Jianlin Hu, Hongliang Zhang
Abstract
The oxidative potential (OP) of fine particulate matter (PM 2.5 ) is a more robust health impact indicator than mass concentration alone. While China’s stringent air pollution controls have significantly reduced PM 2.5 levels, the temporal evolution of OP and its relationship with PM 2.5 remain unclear. This study establishes a national PM 2.5 OP database (2000–2020) using a source-oriented CMAQ model. Key findings reveal that OP decreases alongside PM 2.5 concentrations over the study period, but the decline in OP (16%) is less pronounced than that of PM 2.5 (37%) after 2012, leading to a 35% increase in mass-normalized OP (OP m ). Source apportionment analysis identifies distinct phase-specific drivers: anthropogenic secondary organic aerosols (ASOA) were the dominant contributor to OP increases (∼68%) prior to 2012, while reductions in transportation, power generation, and biomass burning emissions drove OP declines during 2012–2017. Post-2017, stringent controls on anthropogenic non-methane volatile organic compounds (NMVOCs) made ASOA the dominant declining source. Notably, urban-rural disparities in OP exposure exceed those of PM 2.5 mass concentrations, primarily reflecting differences in dominant emission sources. As the first nationwide study to systematically evaluate the decoupling of PM 2.5 mass and OP trends in China, these findings underscore the need for targeted strategies to mitigate PM-related health risks.