Insights into dual-functional modification for water stability enhancement of mesoporous zirconium metal–organic frameworks
Jian Liu, Ryther Anderson, Kevin M. Schmalbach, Thomas R. Sheridan, Zhao Wang, Neil M. Schweitzer, Andreas Stein, Nathan A. Mara, Diego A. Gómez‐Gualdrón, Joseph T. Hupp
Abstract
This study revealed dual functions of the installed Facac ligands: enhancement of framework mechanical stability due to electrostatic interactions; and weaker capillary forces evaluated from free energies of dehydration during water evacuation.
Topics & Concepts
ZirconiumMesoporous materialDual (grammatical number)Materials scienceStability (learning theory)Metal-organic frameworkChemical engineeringNanotechnologyChemistryAdsorptionComputer scienceOrganic chemistryMetallurgyEngineeringCatalysisLiteratureMachine learningArtMetal-Organic Frameworks: Synthesis and ApplicationsEnhanced Oil Recovery TechniquesCovalent Organic Framework Applications