Magnetic properties and magnetocaloric effect of Ln = Dy, Tb carborane-based metal–organic frameworks
Zhen Li, Ana Arauzo, José Giner Planas, Elena Bartolomé
Abstract
We report the synthesis, structure and magneto-thermal properties of two isostructural carborane-based MOFs, {[(Ln) 3 ( m CB-L) 4 (NO 3 )(DMF) n ]·Solv} with Ln = Dy or Tb, characterized by combining dc and ac magnetometry, XAS-XMCD and heat capacity measurements.
Topics & Concepts
Magnetic refrigerationMetal-organic frameworkLanthanideCarboraneMaterials scienceMetalChemistryPhysical chemistryMetallurgyStereochemistryMagnetizationOrganic chemistryPhysicsAdsorptionIonQuantum mechanicsMagnetic fieldMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications