Reversibly Softening and Stiffening Organogels Using a Wavelength-Controlled Disulfide-Diselenide Exchange
M. Mario Perera, Prathyusha Chimala, Abdul Elhusain-Elnegres, Paul Heaton, Neil Ayres
Abstract
Wavelength-dependent light-responsive seleno-sulfide dynamic covalent bonds were used to prepare organogels with reversible changes in stiffness. The disulfide cross-link organogels prepared from norbornene-terminated poly(ethylene glycol) (PEG-diNB) and poly(2-hydroxypropyl methacrylate-stat-mercaptoethyl acrylate) (PEG-diNB-poly(HPMA-stat-MEMA)) polymers underwent exchange reactions with 5,5′-diselenide-bis(2-aminobenzoic acid) upon irradiation with UV light. Following irradiation with visible light, the seleno-sulfide bonds were cleaved, reforming disulfide cross-links and the 5,5′-diselenide-bis(2-aminobenzoic acid). Reduction in G′ with disulfide–diselenide exchange was consistent with that observed following a thiol–disulfide exchange reaction. Recovery of G′ upon disulfide bond formation was 85–95% of the initial value in the as-prepared gel over five cycles of bond cleaving and reformation. This initial study shows the potential of the wavelength-controlled disulfide–diselenide chemistry to develop light-responsive reversible organogels. These organogels have the potential to be used in functional materials such as polymeric actuators or biomimetic soft robotics.